Self-assembly And Logic Function Of Supramolecular Hybrids Based On Polyoxometalates

In recent years, by utilizing supramolecular self-organization and self-assembly method, rapid progresses have been made in material science, life science, nanoscience and so on. Functional assemblies fabricated by supramolecular interactions not only can be used to control the morphology and structures of the functional materials at nanoscale but also may exhibit new properties due to the synergic interaction between each component. Inorganic polyoxometalate is a sort of nanosized poly-anions with defined structures, which have attracted more and more interests due to the versatility in their physical and chemical properties, especially their excellent photo-physical property and have been applied to the fields of biology, material science and so on. Supramolecular building blocks of this functional polyoxometalate material can be constructed by encapsulating polyoxometalate with positively charged surfactants through electrostatic interaction. On the one hand, this building...