| Metallophthalocyanines(MPcs)and metalloporphyrins(MPs)are bioinspired artificial molecules,which present interesting properties for potential applications in different fields.There have been numerous porous materials,including porous organic polymers(POPs)and metalloporphyrinic frameworks(MPFs),based on metallophthalocyanines and metalloporphyrins,have been designed and synthesized,which presented interesting properties for applications in many fields.In this thesis,5,10,15,20-tetrakis-(3,5-biscarboxyphenyl)porphyrine(H10L1)and H10L2 = 5,10,15,20-tetrakis-3,5-bis[(4-carboxy)-phenyl]phenylporphine were used as multidentate bridging ligands to connect with YⅢ ions,and constructed a series of metalloporphyrinic frameworks.We also used a four-branched tetra-amine FePc(TAFP)to react with three-connected 1,3,5-triformylbenzene(TFB),and constructed a 3D porous organic material CZJ-30.These new materials were characterized by single crystal X-ray diffraction,PXRD,FT-IR spectra,thermogravimetric analysis,X-ray photoelectron spectra,elemental analysis,scanning electron microscopy and transmission electron microscopy.The suspended ionic catalyst CZJ-22-Cu demonstrates exceptionally high catalytic efficiency in aerobic oxidation of ethers to esters at room temperature and atmosphere pressure,due to the unique features ofsuspension of redox metal ions inside the anionic pores.CZJ-30 is a 3D porous organic material made from highly photoactive FePc moieties,which demonstrates high photoactivity and stability in photoxidation of arylalkanes under visible light irradiation.The properties of metalloporphyrinic frameworks,CZJ-18(M)(M = CuⅡand ZnⅡ),are systematically tunable by replacing the acetate moieties with different functional moieties,which have been realized applications in aerobic oxidation benzyl alcohol,photocatalytic oxidation of benzyl alcohol and asymmetric aldol addition reaction with high efficiency and selectivity activity. |
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