EXPERIMENTAL DETERMINATION OF THE MELTING CURVE OF MAGNESIUM SILICATE PEROVSKITE AT LOWER MANTLE CONDITIONS, AND ITS GEOPHYSICAL IMPLICATIONS | Posted on:1987-08-06 | Degree:Ph.D | Type:Dissertation | University:University of California, Berkeley | Candidate:HEINZ, DION LARSEN | Full Text:PDF | GTID:1470390017959020 | Subject:Geophysics | Abstract/Summary: | | We present the first static measurement of the melting curve of Mg(,0.9)Fe(,0.1)SiO(,3) (perovskite structure) at lower mantle conditions, demonstrating that it melts at 3000 (+OR-) 300 K independent of pressure over the range of 25-65 GPa. Samples of natural orthopyroxene were compressed in a Mao-Bell type diamond anvil cell and heated using a Nd-YAG laser operating at up to (DBLTURN)25 W in the TEM(,00) mode. The laser beam is focussed to (DBLTURN)35 microns at the sample generating temperature profiles in both the horizontal and vertical directions. To measure the temperature profile, a small sampling slit is scanned across the image of the heated spot. This gives line (strip) integrals across the intensity distribution of the heated spot. A set of line integrals collected at one wavelength can be inverted with an abel transform to obtain the intensity as a function of radial distance. Given the radial intensity distribution at two or more wavelengths, the vertically averaged radial distribution of temperature can be resolved with a spatial resolution of 2-3 microns. Temperature gradients are one the order of 100 K per micron when the sample is solid (T < 3000 K) and 400 K per micron when the sample is partially molten (3000 K < T < 6000 K). The melting point is determined by measuring the lowest peak temperature at which glass is formed in the sample.;The melting temperature of magnesium silicate perovskite places an upper bound on the geotherm of the lower mantle. This upper bound is consistent with either one- or two-layer mantle convection. Our data suggest that the homologous temperature T/T(,m) (DBLTURN) 0.70 or 0.85 for the lower mantle, assuming one or two layer convection, respectively. The flat Clapeyron slope for the fusion curve of perovskite (dT(,m)/dP (DBLTURN) 0 (+OR-) 4 K/GPa), combined with a small but systematic Fe enrichment of the melt (the difference in the mean atomic weight is 4+/-2%) is consistent with the idea that melts sink in the lower mantle. The Clapeyron slope also implies that T/T(,m )(DBLTURN) constant in the lower mantle, suggesting that the viscosity is relatively constant with depth through the lower mantle. | Keywords/Search Tags: | Lower mantle, Melting, Perovskite, Curve, Dblturn | | Related items |
| |
|