In this paper, we use Clifford algebra Cl8 to study the complex structures on R8, unit sphere S6 and S4. We consider Grassmann manifold G(2,8) as a submanifold of the Clifford algebra Cl8. Thus we construct homeomorphism between Grassmann manifold G(2,8) and the set of orthogonal complex structures on R8 by the isomorphism between the Clifford algebra Cl8 and the matrix algebra R(16) .We show that G(2,8) is a totally geodesic submanifold of SO(8). Restricting the homeomorphism on the fibres of fibre bundles π : (7(2,8) → S6 and τ : CP3 → S4 respectively, we get the set of complex structures on the tangent space of S6 and S4 respectively.
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