Electrochemical Synthesis And Characterization Of Transition Metal Cu(â…¡),Zn(â…¡),Ni(â…¡) Complexes With Amino Acid

The transition metal organic complex exhibit function of the light, the electricity, the magnetism, the catalysis, the biochemistry characteristic and so on.The electrosynthesis of metal complexes use pure metal as sacrificing anode and inertia electrode or metal electrode as cathode.Current was passed through the electrolyte solution with supporting electro-condutive additives,Metallic anode was dissolved and reducing reaction occurred on cathode. The main advantage of electrochemical syntheses is that the reaction takes place in one step with high selective , high purity , non-pollution and so on. So the result is especially interesting since they show the possibility of wider application of electrosynthesis in the modern coordination chemistry.Electrosynthesis method is a green chemistry method with sustainable development. The development of electrochemical syntheses in syntheses of transition organometallics was very quick in recent years. In this paper,the main study obtained are as follows:Part one: Electrochemical Synthesis and Characterization of Transition Metal Cu(II),Zn(II),Ni(II) Complexes with a Schiff Base Ligand from Salicylidene and L-isoleucine.The direct electrosynthesis of Cu(II),Zn(II) and Ni(II) complexes of salicylideneamino acid was accomplished by electrochemical dissolution of sacrificial metallic anodes in an acetonitrile solution of the ligand...