As a commonly used hot die material,no effective way was found to elongate the service life of H13 steel.Thus,to find a spray technique and material for the surface strengthening and repairing,the High Velocity Oxygen Fuel spray process and means of oxyacetylene flame spray-welded process were employed to create Cr3C2-NiCr coating and Ni60 A coating on the surface of H13 in this paper.Considering the surface finish,microhardness and shear bond strength of the coating,the microstructures,phase structures and interface adhesion mechanism of all the powder and coating.Also the experiment of thermal fatigue property and high temperature friction and wear behavior on the coating were conducted.The microstructure of two obtained coating is evenly distributed and cohesively bound layer by layer.Cr3C2-NiCr coating and the base are mechanically combined,while Ni60 A coating and the base are metallurgically combined.Aside from phases of Cr3C2,NiCr which were contained in the coating material of Cr3C2-NiCr coating,small amount of Cr7C3,Cr2O3 coexisted due to the burning loss and the oxidation of carbon during spray process.It turned out that there is no big difference between the base and Ni60 A coating which is comprised of γ-(Ni,Cr),(Fe,Ni)23C6,carbide and boride of Cr,etc.The results show that Cr3C2-NiCr coating has the highest microhardness,followed by Ni60 A coating and H13 comes third.While microhardness of Ni60 A coating is more stable than that of the Cr3C2-NiCr coating.At room temperature and the temperature of 600℃,shear bond strength between Ni60 A coating and the base is obviously better than Cr3C2-NiCr coating,contrary to the thermal fatigue property at the temperature of 400℃ and 600℃.In the high temperature friction and wear behavior experiment at the temperature of 400℃,there is no much difference in the wearing depth between Cr3C2-NiCr coating and H13.But with the rise of temperature,high-temperature wear resistance of Cr3C2-NiCr coating better than that of H13 evidently.When reaching the temperature of 600℃,the wearing depth of H13 is as twice as much in Cr3C2-NiCr coating,yet pretty the same as H13 in 400℃600℃. |