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The Preparation,Characterization And Heterogeneous Fenton-Like Catalytic Properties Of The Iron Silicate

Posted on:2018-09-13Degree:MasterType:Thesis
Country:ChinaCandidate:Z H ZengFull Text:PDF
GTID:2381330542973320Subject:Inorganic Chemistry
Abstract/Summary:PDF Full Text Request
The heterogeneous Fenton-like process has a significant advantage in the field of wastewater treatment for its efficient oxidizability to degrade the high concentration and non-biodegradable dye wastewater.It can predict that the development of Fenton-like catalyst with environmental friendly,high efficiency,low energy consumption,and study the dynamics of the treatment of organic wastewater,understand the reaction mechanism and other scientific problems of this system is key to research of that field,and the main direction of future environmental organic pollution control technology.In this work,we synthesized Fe2?SiO3?3,Fe1.8Cr0.2?SiO3?3 and Fe1.89Cu0.21?SiO3?3 by low temperature solid state method,and the poly-silicic-ferric was prepared using Na2SiO3·9H2O,FeCl3·6H2O by co-polymerization.The physical and chemical properties of catalyst characterized by XRF,XRD,FT-IR,XPS and FESEM.The methylene blue was used as the probe molecule,and the catalytic activity for catalyze H2O2 oxidation of MB was evaluated.The effect of pH,H2O2 concentration,reaction temperature,catalyst dosage on the catalytic performance of catalyst were investigated.The results shows that all of them are efficient Fenton-like catalyst and can be separated easily.
Keywords/Search Tags:Low-temperature solid-state reaction, Heterogeneous Fenton-like process, Iron Silicate, poly-silicic-ferric
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