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Rates of reaction of sulfur trioxide and sulfuric acid with calcium oxide particles

Posted on:2011-08-20Degree:M.SType:Thesis
University:Lehigh UniversityCandidate:McMullen, David PatrickFull Text:PDF
GTID:2441390002462321Subject:Engineering
Abstract/Summary:
In this thesis the use of CaO as a sorbent for the reduction of SO 3 and H2SO4 in flue gas from a power plant was examined. An apparatus was designed to create SO3 by oxidizing SO2 then in turn adding H2O to bond with the SO 3 to make sulfuric acid (H2SO4). This gas containing sulfuric acid is then passed through a bed of CaO and analyzed to examine the remaining content of H2SO4. A separate sampling apparatus was designed to sample the gas before and after entering the CaO bed. Experiments were performed for various temperatures, residence times, and H2O contents. A model for predicting the capture of H 2SO4 was developed from the experimental data.
Keywords/Search Tags:Sulfuric acid, H2SO4
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