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Synthesis and photoluminescent properties of starburst compounds based on 7-azaindole, indole and 3-methyl indole

Posted on:2006-02-17Degree:M.ScType:Thesis
University:Queen's University at Kingston (Canada)Candidate:Huang, WeihuaFull Text:PDF
GTID:2451390008971929Subject:Chemistry
Abstract/Summary:
The subject of this thesis is the synthesis of a series of star-shaped compounds based on 7-azaindole, indole and 3-methyl indole. All of these organic compounds have highly pi-conjugated structures with different cores such as benzene, 1,3,5-triazine.; New 7-azaindole derivatives, 2,4,6-tris(1-N-7-azaindolyl)-1,3,5-triazine (S1), 1,3,5-tris[p-(1-N-7-azaindolyl)phenyl]benzene (S2), 2,4,6-tris[p-(1-N-7-azaindolyl)phenyl]1,3,5-triazine (S3) have been synthesized and fully characterized. The photoluminescent and electronic properties of these compounds were studied.; Novel indole and 3-methyl indole derivatives, 1,3,5-tris[3,5-bis(N-indolyl)-4 '-biphenyl]benzene (S5), 2,4,6-tris[3,5-bis(N-indolyl)-4 '-biphenyl]-1,3,5-trizine (S6), 1,3,5-tris[p-[ N-(3-methyl-indolyl)]phenyl]benzene (S4), 1,3,5-tris[3,5-bis[ N-(3-methyl-indolyl)]-4'-biphenyl]benzene (S7) have been synthesized and characterized. The photoluminescent and electronic properties of these compounds were investigated.; The synthetic strategies for this series of molecules involve N-arylation at mild temperature and Suzuki Cross-coupling reactions.
Keywords/Search Tags:Indole and 3-methyl, Compounds, Photoluminescent
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