| In this paper,the biochar was first prepared by KOH activator using the rape straw.Then the Fe3O4/biochar was obtained by coupling the Fe3O4 with the above biochar.Last,the biochar was fabricated by one-step method using Zn Cl2 as the activator.The three types of biochar materials were respectively applied for the adsorption of tetracycline hydrochloride and ciprofloxacin hydrochloride antibiotics in water.The X-ray diffraction(XRD),scanning electron microscopy(SEM),N2adsorption-desorption,Fourier transform infrared spectroscopy(FTIR)test techniques were adopted to study the crystal phases,morphologies,specific surface areas and surface functional groups of biochar materials,respectively.The effects of preparation conditions and solution p H value on the adsorption capacity were also explored.The adsorption kinetics and adsorption isotherms were employed to investigate the adsorption process.The current work will offer some new ideas for the utilization of rape straw agricultural wastes. |