Hydrothermal Synthesis And Research Of Indium Phosphates And Titanium Phosphates With Open-framework

Inorganic microporous materials have popular application in catalysis, adsorption, ion-exchange, separation and host-guest assemblies due to their unique pore architectures. And the rational design and synthesis of new microporous compounds, as well as the development of new synthetic ways are becoming the topics of microporous chemistry. In the last decade, the synthesis of new materials that might combine the nanoporosity of zeolites with the magnetic and optical properties, electronic conductivity and ferroelectric of main group metal transition metal phosphates such as AlPOs, GaPOs, InPOs, TiPOs, VPOs, FePOs, ZnPOs and CoPOs have been reported in the literatures. Many of theses materials exhibit unique structures and may have potential applications in catalysis and another fields. In addition, these compounds have great significance in crystallography and the study of biomineralization.The goal of this work is to synthesis and preparation of Indium phosphates and Titanium phosphates continuously and systematically by hydrothermal conditions. And also to explore the synthetic rules and potential transformation from lower dimensional structure to higher dimensional ones.1. In In(OH)₃-P₂O₅-amine-HF-H₂O system, fourteen indium phosphate...