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Study of use of hybrid materials obtained by sol-gel to produce efficient pre-treatments to prevent galvanized steel reinforcement corrosio

Posted on:2015-10-01Degree:Ph.DType:Dissertation
University:Universidade do Minho (Portugal)Candidate:Figueira, Rita Maria Burguete Bacelar MarreirosFull Text:PDF
GTID:1451390005982418Subject:Chemistry
Abstract/Summary:
This study is focused on the development of OIH coatings for HDGS reinforcement in contact with cementitious media. OIH sol-gel matrices doped and undoped with inhibitors, ureasilicate and alcoholaminosilicate, were synthesized. The coatings were deposited on HDGS by a dipping process. The barrier efficiency of the different OIH sol-gel coatings was studied and assessed by several electrochemical techniques and surface analysis, when in contact with cementitious materials (cement pastes and mortar). The results show that the OIH sol-gel coatings studied effectively allow the mitigation of harmful effects of the initial excessive reaction between cementitious materials and the HDGS, showing promising properties to be used as eco-friendly pre-treatments on HDGS in contact with cementitious media.
Keywords/Search Tags:Contact with cementitious, HDGS, OIH sol-gel, Materials, Coatings
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