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Experimental transport studies of yttrium barium copper oxide and lambda-DNA

Posted on:2004-07-17Degree:Ph.DType:Dissertation
University:Princeton UniversityCandidate:Zhang, YuexingFull Text:PDF
GTID:1451390011953298Subject:Physics
Abstract/Summary:
This dissertation consists of two parts.; In Part I, we focus on the quasi-particle transport properties in the high temperature superconductor YBa2Cu3O7−δ (YBCO), probed by the thermal Hall conductivity (κ xy). The thermal Hall conductivity selectively reflects the transport behaviors of the charge carriers.; By measuring κxy in the normal state YBCO, we established a new method to determine the Wiedemann-Franz (WF) ratio in cuprates. We determined the Hall-channel WF ratio κ xyxyT in Cu and YBCO. In the latter, we uncovered a T-linear dependence and suppression of the Hallchannel WF ratio. The suppression of the Hall-channel WF ratio in systems with predominant electron-electron scattering will be discussed.; Thermal transport behaviors of the quasi-particles in the mixed state were studied by measuring κxx and κ xy in a high-purity YBCO crystal. From the field-dependence of the thermal conductivity κxx, we separated the quasi particle contribution (κe) from the phonon background. In the Hall channel, we observed that the (weak-field) κ xy increased 103-fold between T c (90 K) and 30 K, implying a 100-fold enhancement of the quasi-particle lifetime. We found that κxy exhibited a specific scaling behavior below ∼30 K. The implication of the scaling behavior will be discussed.; In Part II, we describe an experiment on determining the electrical conductivity of the bacteriophage λ-DNA, an issue currently under intense debate. We covalently bonded the DNA to Au electrodes by incorporating thiol modified dTTP into the ‘sticky’ ends of the λ-DNA. Two-probe measurements on such molecules provided a lower bound for the resistivity ρ > 10 6 μm at bias potentials up to 20 V, in conflict with recent claims of moderate to high conductivity. We stress the importance of eliminating salt residues in these measurements.
Keywords/Search Tags:Transport, WF ratio, Conductivity, YBCO
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