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Durable Nanocomposites for Superhydrophobicity and Superoleophobicity

Posted on:2012-01-30Degree:Ph.DType:Dissertation
University:University of VirginiaCandidate:Steele, AdamFull Text:PDF
GTID:1451390011953410Subject:Chemistry
Abstract/Summary:
Anti-wetting surfaces and materials have the potential for dramatic performance improvements such as drag reduction on marine vehicles and fluid power systems as well as anti-fouling on aircraft and wind turbines. Although a wide variety of synthetic superhydrophobic surfaces have been developed and investigated, several critical obstacles remain before industrial application can be realized, including: (1) large surface area application, (2) multi-liquid anti-wetting, (3) environmentally friendly compositions, (4) mechanical durability and adhesion, and (5) long-term performance. In this dissertation, nanocomposite coatings have been investigated to generate high performance anti-wetting surfaces that address these obstacles which may enable application on wind turbine blades. Solution processable materials were used which self-assemble to create anti-wetting nanocomposite surfaces upon spray coating and curing. As a result, the first superoleophobic nanocomposite, the first environmentally friendly superhydrophobic compositions, and the first highly durable superhydrophobic nanocomposite coatings were created. Furthermore, the mechanisms leading to this improved performance were studied.
Keywords/Search Tags:Nanocomposite, Superhydrophobic, Performance, Surfaces
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