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Systems of nonlinear equations deriving from complex chemical reaction networks

Posted on:2003-06-20Degree:Ph.DType:Dissertation
University:The Ohio State UniversityCandidate:Craciun, GheorgheFull Text:PDF
GTID:1460390011481853Subject:Mathematics
Abstract/Summary:
The capacity for multiple equilibria in an isothermal homogeneous continuous flow stirred tank reactor is determined by the reaction network. Examples show that there is a very delicate relationship between reaction network structure and the possibility of multiple equilibria.; Previous results of Schlosser and Feinberg are sufficiently refined as to identify subtle differences between networks that can admit multiple equilibria and very similar ones that cannot, based on a graph associated to the reaction network, called the SCL graph. The SCL graph method cannot be easily implemented as a computer algorithm, and does not give an answer for some reaction networks.; We suggest two new methods of solving this problem. One method can be implemented as a simple computer algorithm, and is more general than the SCL graph method. The other method is based on a new type of graph associated to the reaction network, called the SR graph, and gives an answer for many reaction networks for which the SCL graph method does not.
Keywords/Search Tags:Reaction, SCL graph method, Multiple equilibria
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