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The microflow behavior and interphase characterization of fiber-reinforced polymer composites

Posted on:2004-11-29Degree:Ph.DType:Dissertation
University:University of DelawareCandidate:Foley, Maureen ElizabethFull Text:PDF
GTID:1461390011959741Subject:Engineering
Abstract/Summary:
There is typically a trade off that takes place when designing a composite part for ballistic purposes. Structural strength requirements typically call for less than 1% voids with strong adhesion between the fiber and matrix whereas for ballistic applications, such as spall plates for body armor where energy absorbing properties are paramount, the composites are usually resin lean and have weaker fiber matrix interphases. The energy absorbing properties of a composite can be tailored through the sizings applied to the fiber or through control of the resin infiltration of the composite part.; The goal of this research was two pronged. The first was to develop a transverse microflow model that could be used to predict the microflow within a tow assuming it is completely surrounded by resin. The models developed consider the capillary pressure on the flow front, which is typically ignored by literature models, as the main driving force for transverse flow into the fiber bundles. This capillary pressure is a function of the surface properties of the resin and fiber and by tailoring these properties one can control the microflow of the resin. The dynamic model, which takes into account the fiber radius, fiber volume fraction, fiber count, resin contact angle with the fiber and the resin surface tension, was used to study the effects of tow count, fiber volume fraction and contact angle on the infiltration time.; The second goal of this research was the development of an interphase characterization methodology that can be used to evaluate the interphase properties, using the Dynamic Interphase Loading Apparatus (DILA), once the fiber preforms are infiltrated. The DILA is a unique piece of equipment that allows one to pushout a fiber from a thin composite slice while recording the resulting force and displacement. The interphase characterization process includes indenter selection, sample and test configuration design, test parameters, post test validation and data reduction. This process was used to evaluate glass fiber reinforced epoxy and vinyl ester systems under quasi-static and cyclic loading as examples of the DILA capabilities.
Keywords/Search Tags:Fiber, Composite, Interphase characterization, Microflow, DILA
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