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Electrochemistry and spectroelectrochemistry of (A) fullerenes and related materials, and (B) metalloporphycenes

Posted on:1996-07-02Degree:Ph.DType:Dissertation
University:University of HoustonCandidate:Boulas, Pierre LouisFull Text:PDF
GTID:1461390014488061Subject:Analytical Chemistry
Abstract/Summary:
his dissertation consists of two major parts. In the first part, Part A, the research accomplished in the field of fullerene and related materials is described: (1) The redox and spectral properties (UV-visible and IR) of C;In the second part of this dissertation, Part B, the electrochemistry and spectroelectrochemistry of metalloporphycenes are described: (1) Octaethylporphycenes containing first-row transition metals were examined using electrochemistry, UV-visible spectroelectrochemistry and ESR spectroscopy. Spectral criteria were established to distinguish ring-centered and metal-centered electron transfers. (2) Various...
Keywords/Search Tags:Electrochemistry, Part
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