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Fine structure and Zeeman effect of the b triplet state of lithium dimers

Posted on:1988-03-16Degree:Ph.DType:Dissertation
University:The Pennsylvania State UniversityCandidate:Jeng, Wen-HawFull Text:PDF
GTID:1470390017958043Subject:Physical chemistry
Abstract/Summary:
The various perturbations among the low lying electronic states of Li;While the magnetic rotation spectra (MRS) of other alkali metal dimers in the A;In this work, the A;Two types of high resolution techniques were used to resolve the closely spaced levels: the intermodulated fluorescence spectroscopy and the Doppler-free polarization spectroscopy. Measurements were made in magnetic fields up to 3 kG using a CW single mode dye laser. Switching to two different experimental schemes, the ;An irreducible tensor method was used to derive the fine structure and Zeeman Hamiltonian matrix elements in symmetrized case (b) basis functions. The matrix elements evaluated in case (a) basis functions are also given.;While the spin-orbit constant of the b...
Keywords/Search Tags:Fine structure and zeeman, Matrix elements, Basis functions
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