GEOLOGY OF REDBED COPPER-URANIUM OCCURRENCES IN THE UPPER DEVONIAN CATSKILL FORMATION, PENNSYLVANIA

A regional and detailed geologic, petrographic and geochemical study of 40 redbed Cu-U occurrences and the host Upper Devonian Catskill Fm. in Pennsylvania shows that depositional environment and diagenetic processes were the most important controls on the formation of the occurrences. The Catskill Fm. in Pa. has been divided into 4 magnafacies (Mf) using published sections and 10 new sections. In ascending order, Mf-A contains interbedded marine and non-marine shale and fine sandstones; Mf-B contains mainly thick red shales and thin sandstones interpreted to be low-energy fluvial deposits on an inactive coastal plain interrupted by occasional thin transgressive marine sandstones. Mf-C is composed of thick sandstones deposited by braided rivers; and Mf-D is composed of thick fining-up cycles deposited by meandering rivers. The Cu-U occurrences are located in areas of thick Mf-B between three major northwest-trending sand-rich sediment-input centers defined by thick Mf-C and -D; they occur in Mf-A, -B and -D. Cu-sulfides formed during diagenesis with chlorite in pockets of plant trash within or below a marine or fluvial sandstones, which contain a greater percentage of ductile grains than similar sandstones are inferred to have been more permeable than 'non-mineralized' sandstones. The Cu-sulfides formed after early hematite, clay coatings and calcite cement. Based on isotopic, textural and compositional evidence, the calcite is considered to have formed near the surface at temperatures of less than 100(DEGREES)C from oxidizing waters reduced by plant material. The Cu and U in a typical occurrence could easily have been derived by leaching of 1-3% of the total Cu and U from a volume of sediment equivalent to a cube of 40 m or less on a side. Cu appears to have been mobilized during compaction and was derived from the fine fraction of the sediments by Cl-bearing solutions introduced during marine transgressions. The S was similarly derived by bacterial reduction of sulfates from the originally marine pore waters. Only a small proportion of the mobilized Cu and U was fixed, because of the small volume of reduced fossil plant material.