Bromination of carbon fibers and carbon-carbon composites | Posted on:1991-10-12 | Degree:Ph.D | Type:Dissertation | University:State University of New York at Buffalo | Candidate:Ho, Chi-Ting | Full Text:PDF | GTID:1471390017951098 | Subject:Engineering | Abstract/Summary: | | Bulk chemical modification of carbon fibers and carbon-carbon composites was performed by bromination for the purposes of increasing the oxidation resistance and decreasing the electrical resistivity.;Two methods of bromination were used, namely exposure to Br;Bromination did not degrade the tensile properties of the Amoco Thornel P-100 fibers, as previously reported by others, but it decreased the tensile modulus by up to 17% for the du Pont E-130 fibers and the carbon-carbon composites that had been heat treated up to 2000;The oxidation rate measured at 25% burn-off at 650;Both purposes were achieved in Amoco Thornel P-100 pitch-based carbon fibers and in carbon-carbon composites that had been heat treated up to 2000;The activation energy for bromine desorption was found to increase with increasing degree of intercalate order and decrease with increasing degree of graphitization. | Keywords/Search Tags: | Carbon-carbon composites, Carbon fibers, Bromination, Amoco thornel P-100, Increasing | |
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