Separation of Industrially-Relevant Gas Mixtures With Metal-Organic Frameworks
Posted on:2015-05-11
Degree:Ph.D
Type:Dissertation
University:University of California, Berkeley
Candidate:Herm, Zoey Rose
Full Text:PDF
GTID:1471390017991913
Subject:Chemistry
Abstract/Summary:
The work herein describes the investigation of metal-organic frameworks for industrial applications, specifically gas phase separations of mixtures. Metal-organic frameworks are crystalline molecular scaffolds built from cationic metal vertices and organic bridging ligands. They are porous on a molecular scale and can separate gas mixtures when one component interacts more strongly with the pore walls than others. The near-infinite combination of metals and ligands allows for optimization of metal-organic framework structures for specific separations. (Abstract shortened by UMI.).