Synthetic And Stuctural Studies Of Series Of Chiral Ligands And Their Sn Complexes Derived From (1R, 2R)-(-)-1, 2-Diaminocyclohexane

This thesis shows some work and findings as following:The research background of relative work is introduced in details in chapter one. In this chapter we describes the electron bonding, structural features and synthetic methods of organometallic complexes with aminometallanes and delocalised η3-πamidinate ligand.Chapter two is concerned with the syntheses and characterization of some chiral ligands and consists of relevant mechanism of reaction( for example, N anion acts as nucleophilic reagent and different nitriles act as reacting substance) . They have been structurally characterized and their spectroscopic behaviors are studied .Chapter three describes two compounds of stannum and includes their synthetic methods, synthetic routines and reactivities. They have been identified by X-ray diffraction study.Chapter four deals with the synthesis , spectroscopic and structural study of two novel chiral annuloid compounds derived from 1,2-diaminocyclohexane (DACH) via silicon and phosphor.Chapter five is conclusion and prospects. It includes a summary of the previous work and gives prospects of the future work.