The Growth And Character Research Of One Dimension Carbon Nanomaterial | Posted on:2006-02-16 | Degree:Master | Type:Thesis | Country:China | Candidate:H J Li | Full Text:PDF | GTID:2121360155460767 | Subject:Materials Physics and Chemistry | Abstract/Summary: | PDF Full Text Request | Carbon nanotubes may have huge potential for future technology because of their superior electrical, mechanical, and chemical properties. For the study of electrical properties, individual high-aspect-ratio carbon nanofibers were grown in plasma enhanced hot filament chemical vapor deposition. The carbon nanofibers are 60–100 nm in diameter and 6–30 μm in length, with a density less than 106/cm2. Field emission data from individual carbon nanofibers have been measured using a small-diameter moveable probe. The field-emission properties were then studied. The field emission characteristics of CNFs showed a turn-on field about 5 V/μm, the field-emission current of 5 V/μm was 20 μA/cm2, less than the field emission characteristics of carbon nanotubes . The experimental results vary with the length of CNFs and the position of a CNF, that indicate the field-emission properties decided from the work function of materials, applied field and field amplification factor. Furthermore, the dispersion with defection is the key factor that decides the field-emission current. At the same time, the electric transport properties of a single MWCNT without any post processing were studied in situ at room temperature in a scanning electron microscope chamber (SEM) equipped with a moveable probe. It is found that the as-grown single MWCNT has the capacity of carrying a large current with extremely stable high current densities of 107 A/cm2, as well as a very low resistance (about 34.4?) and high conductance (much larger than the quantum conductance G0). In addition, the measurement of a single MWNT at different points demonstrated almost the same current-voltage characteristics. The experimental observation implies a quasi-ballistic conducting behavior occurring in the as-grown MWCNTs of large diameter, which can be attributed to the mechanism of multiple channels conducting.
| Keywords/Search Tags: | PECVD, HFCVD, carbon nanotube, carbon nanofiber, field electron emission | PDF Full Text Request | Related items |
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