In recent years, titanium dioxide (TiO2) has been a popular photocatalyst for the treatment of organic pollutants in water and air. However, TiO2 photocatalysts have an inherent and significant drawback; that is, the photogenerated charge carriers (hole-electron pairs) can recombine. Therefore, to increase the photocatalytic activity of TiO2, it is important to decrease the recombination of photogenerated charge carriers. Coupling TiO2 with other semiconductors can provide a beneficial solution for this drawback. TiO2 and SnO2 are rutile crystal, but have different property. The energy gaps of these two semi-conductors are match, which can prevent the recombination of photogenerated charge carriers,and show efficient photoactivity.This dissertation consists of following contents.1. The sol-gel technique has been used to prepare SnxTi1-xO2 composite oxide with different amounts of Sn. X-ray diffraction (XRD), was used to characterize the phase transition at different heat treatment temperature. In some way, Sn doping promote the phase transition from anatase phase to rutile phase and the grain size of the SnxTi1-xO2 composite is smaller than that of TiO2.2. The photo-catalyst tests was evaluated by decomposition of methylene blue and neutral red solution. As a result, the SnxTi1-xO2 composite oxides show a more efficient photoactivity for degradation of methylene blue and neutral red in solution, and the photo-catalyst activity is different when x is different in the SnxTi1-xO2.3. Sol - gel method was prepared by Sn-Li-F co-doped photocatalyst of TiO2. Using the degradation of methylene blue photo-catalyst in aqueous solution, it was found that photocatalytic degradation of methylene blue solution with the light absorbance time index similar to obey the law. By comparing the solution of methylene blue light of life to evaluate the photocatalytic efficiency of the catalyst. Sn-doped single time, optimize the molar ratio of 5% of doping and heat treatment temperature of 600℃. At times on this foundation to further the formation of LiF 3%-doped Sn-Li-F ternary è¿‘å¹´æ¥,TiO2作为一ç§ç”¨é€”很广的åŠå¯¼ä½“ææ–™,å› å…¶æ´»æ€§é«˜,稳定性好,å¯¹äººä½“æ— æ¯’,æˆæœ¬ä½Žä¸”在光催化处ç†æ±¡æŸ“水和空气ä¸å·²å¹¿æ³›åº”用,而æˆä¸ºæœ€å…·æ½œåŠ›çš„光催化剂。然而TiO2本身有其固有的缺陷,光生电å-空穴对容易å¤åˆ,è¿™é™ä½Žäº†å…¶å…‰å‚¬åŒ–æ´»æ€§ã€‚å› æ¤,è¦æ高TiO2的光催化活性,就应å‡å°‘光生电å与空穴的å¤åˆã€‚å…¶ä¸å°†TiO2与其它氧化物åŠå¯¼ä½“å¤åˆå¯èƒ½æ˜¯æ高其光催化活性途径之一。TiO2å’ŒSnO2都是有金红石型的晶体结构,但是性质差别很大,这两ç§åŠå¯¼ä½“æ料能级匹é…,光生电å和空穴å¯ä»¥å‘生有效的分离,使它们å¤åˆå‡ 率å‡å°,从而å¯ä»¥æ高TiO2的光催化活性。本文主è¦ç ”究内容如下:1.利用溶胶-å‡èƒ¶æ³•åˆæˆäº†SnxTi1-xO2å¤åˆæ°§åŒ–物,考察了ä¸åŒé€€ç«æ¸©åº¦å’Œä¸åŒçš„锡å«é‡å¯¹æ料晶型的影å“。采用x-射线è¡å°„(XRD)对åˆæˆæ料进行了分æžè¡¨å¾ã€‚结果表明,SnxTi1-xO2å¤åˆæ°§åŒ–物ä¸é”¡ä¿ƒè¿›äº†äºŒæ°§åŒ–é’›ä¸é”钛矿相å‘金红石相的转å˜,ä½†é”¡çš„åŠ å…¥èƒ½æŠ‘åˆ¶æ料颗粒的生长,TEM表å¾è¯´æ˜ŽSnxTi1-xO2å¤åˆæ°§åŒ–物的粒径比纯TiO2的粒径è¦å°ã€‚2.利用亚甲基è“è¿™ç§å¶æ°®æŸ“料水溶液对åˆæˆçš„æ料进行了光催化活性测试,测试结构表明,SnxTi1-xO2å¤åˆæ°§åŒ–物的光催化活性比纯TiO2的光催化活性è¦å¥½,并且SnxTi1-xO2å¤åˆæ°§åŒ–物ä¸é”¡æŽºæ‚é‡ä¸åŒå…¶å‚¬åŒ–活性也ä¸åŒ,å•ä¸€æŽºæ‚Snæ—¶,优化出5%的摩尔比掺æ‚é‡å’Œ600℃的çƒå¤„ç†æ¸©åº¦ã€‚3.溶胶-å‡èƒ¶æ³•åˆ¶å¤‡äº†Sn-Li-F共掺æ‚çš„TiO2光催化剂。采用该催化剂光助é™è§£äºšç”²è“水溶液时,å‘现光催化é™è§£äºšç”²åŸºè“溶液的å¸å…‰åº¦éšå…‰ç…§æ—¶é—´çš„å˜åŒ–è¿‘ä¼¼æœä»ŽæŒ‡æ•°è§„律。通过比较亚甲基è“溶液的光照寿命以评价催化剂的光催化效率。在å•ä¸€æŽºæ‚Sn基础上进一æ¥æŽºæ‚LiF 3%å½¢æˆSn-Li-F三元共掺æ‚çš„TiO2光催化剂,ç»500℃çƒå¤„ç†åŽ,å…‰é™è§£äºšç”²è“的效率åˆæœ‰æ高。...
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