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Study On The Denitrification And Combustion Mechanism Catalysis By Nano-TiO2

Posted on:2010-02-17Degree:MasterType:Thesis
Country:ChinaCandidate:H Y KongFull Text:PDF
GTID:2121360275984983Subject:Environmental Engineering
Abstract/Summary:PDF Full Text Request
NOx is one of the main pollutants during coal combustion. It cannot only cause the corrosion of the equipment, but also can cause the acid dust and acid rain. Using nano-TiO2 as the catalyst to desulfurization and denitrification also could make the burning completely. In the condition of desulfurization by CaO or non CaO, it discussed the efficiency of denitrification by nano-TiO2 in the process of coal burning. The following conclusions were: the desulfurization and denitrification efficiencies reached 87.8% and 36% when the additive of nano-TiO2 was 8%, the optimum molar ratio of Ca to N was 1.22, the burning temperature was 850℃and the flux of oxygen reached 40 ml/min. The flue gas was analyzed by the Flue Gas Analysis and Ion Chromatography(IC), the specific surface area of coal char was analyzed. The combustion catalysis mechanism of nano-TiO2 includes homophase reduction and heterogeneous reduction. Nano-TiO2 is helpful to the conversion of NOx to N2 by analyzing the conversion of NO redacted by coal char.
Keywords/Search Tags:nano-TiO2, catalytic burning, denitrification, reaction mechani
PDF Full Text Request
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