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Photodegradation Of Phenanthrene Catalyzed By Nano-TiO2

Posted on:2011-01-09Degree:MasterType:Thesis
Country:ChinaCandidate:W LuFull Text:PDF
GTID:2121360305985214Subject:Microbial and Biochemical Pharmacy
Abstract/Summary:PDF Full Text Request
属性不符 phenanthrene, the degradation rate decrease and the degradation rate decrease greatly when the concentration of phenanthrene reaches a certain value. High and low pH value can be conductive to the degradation rate. The addition of Fe3+can increase the degradation rate, but when the Fe3+ concentration is above 0.6mmol/L, the degradation rate began to fall and it can reduce the degradation of phenanthrene when the Fe3+ concentration is more than 1.2mmol/L.K2S2O8 can accelerate the degradation of phenanthrene. With the increase of NaHCO3, the degradation rate decrease.In the treatment of water with phenanthrene by photocatalytic oxidation used nano-TiO2 ceramic ball as catalyst, we found that the temperature, value of pH, Ca2+ have no significant effect on the degradation of phenanthrene. With the increase of phenanthrene, the degradation rate decrease. Fe3+ and K2S2O8 can accelerate the degradation of phenanthrene. With the increase of NaHCO3, the degradation rate decrease The photocatalytic degradation rate gradually decreased from 96.09% to 73.97% after eight times repeated use. In the process, some intermediate products were detected by GC-MS, the pathway of phenanthrene degradation was described.
Keywords/Search Tags:Polycyclic aromatic hydrocarbons, phenanthrene, nano-TiO2 ceramic ball, photocatalytic degradation
PDF Full Text Request
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