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The Research Of Prussian Blue And Its Derivates As Material Of Solid Battery

Posted on:2007-10-28Degree:MasterType:Thesis
Country:ChinaCandidate:J H ZhaoFull Text:PDF
GTID:2132360185487326Subject:Applied Chemistry
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As the first polymer which was synthesized by human, Prussian blue has been studied in many scopes from 1704 when it was discovered. The studied object was from the Prussia oneself to its derivatives, applied realm has been expendied continuously. Prussian blue and its derivatives are polymers that have three dimensionalities net structures of the zeolite character, have many excellent characteristics like electrochemistry reversibility, high stability, low cost and easy synthesis. As a result, Prussian blue and its derivates that there will be latent applied foreground at polymer secondary battery.This text studied the Prussian blue and its derivatives that have been studied at polymer secondary battery. With the K3Fe(CN)6 and K4Fe(CN)6·3H2Ofor raw material, polymer 1-------[FeFe(CN)6·aq] and polymer 2------[KFeFe(CN)6 ? aq] have been Synthesized, and characterized with XRD,IR and conductance ratio. The end confirmated polymer 1 is [FeFe(CN)6·4.5H2O], polymer 2 is [KFeFe(CN)6·6H2O]. They both all have three dimensionalitiesspace structures of type of cube. Their crystal constant are 5.0778 A ([FeFe(CN)6· 4. 5H2O] ) , 5. 0953 A ( [KFeFe(CN)6 ? 6H20] ) . Indoor...
Keywords/Search Tags:solid electrolyte, ion conductance ratio, cell, Prussian blue
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