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Layered Photocatalytic Materials K <sub> 2 </ Sub> La <sub> 2 </ Sub> Ti <sub> 3 </ Sub> O <sub> 10 </ Sub> Preparation And Properties Of,

Posted on:2003-08-07Degree:MasterType:Thesis
Country:ChinaCandidate:L L ZhangFull Text:PDF
GTID:2191360095952485Subject:Applied Chemistry
Abstract/Summary:PDF Full Text Request
Because of its full of active reaction points, Perovskite-type layered composites become one of the most important kind of photocatalytic materials and will be widely used in overall water splitting . This dissertation was mainly discussed on K2La2li3O10. A series of K2La2li3O10. with different sizes were obtained by Solid-State reaction using TiO2 with different average particle sizes as raw material. The products were characterized by X-ray diffraction (XRD), transmission electron microcopy (TEM), thermogravity analysis (TG), Fourier transform infrared spectroscopy (FT-IR) experiments. It was found that the average size of the TiO2 influents the solid-state reaction, the morphology of the layered titanates, H+-exchanging, alkylamine-intercalation, pillaring and exfoliation properties of the layered K2La2li3O10. . Ultrafine layered K2La2li3O10. was successfully fabricated by stearic acid method for the first time and it was easily exfoliated in HNO3. In the H+-exchanging section, four different kinds of acid were used and the influence of the acid on the layer structure of the products was studied . It was raised that the layer structure of the products was mainly effected by the anion of the acid . For the first time we attempted to pillar CdS into the layered K2La2li3O10. in order to enhance its photocatalytic activity and we had done it successfully.
Keywords/Search Tags:photocatalysis, layered titanates, H+-exchanging, alkylamine-intercalation, pillaring, exfoliation
PDF Full Text Request
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