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The Nature Of The Lsco Thin Film Conductive Properties Of Laser-induced Voltage

Posted on:2006-10-01Degree:MasterType:Thesis
Country:ChinaCandidate:J L WangFull Text:PDF
GTID:2191360185953597Subject:Materials science
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La0.5Sr0.5CoO3 has being applied in fuel cells, gas sensors and as electrodes in ferroelectric memories due to its relatively high electronic and ionic conductivity. Since La0.5Sr0.5CoO3 has a pseudo-cubic perovskite structure, excellent structural companionate with Pb-based oxide perovskite ferroelectrics, La0.5Sr0.5CoO3 been used as the electrode, which can improve the fatigue of ferroelectric memory cells. So the future of the La0.5Sr0.5CoO3 as a conductive material is hopefully.We prepared the La0.5Sr0.5CoO3 films on SiO2/Si (004), SiO2/Si (111) and LaA1O3 substrates by pulsed laser deposition method using the high quality La0.5Sr0.5CoO3 polycrystalline targets. The growth conditions, structures, surfaces morphology and resistance of the films. We studied the dependences between the resistance and humidity, temperature. Moreover, we detected the laser induced thermoelectric voltage in the La0.5Sr0.5CoO3 films on vicinal LaAlO3 substrates.The main results and conclusions include:1. We measured and calculated the resistivity of the La0.5Sr0.5CoO3 target, and provided the reliable data.2. We studied the condition of the La0.5Sr0.5CoO3 growth on SiO2/Si (004), SiO2/Si(111) LaA1O3 substrates. We get the film which is preferential orientation on SiO2/Si substrates. We calculated the films' resistivity. We also get the La0.5Sr0.5CoO3 films which is grown epitaxial on LaAlO3 substrates.3. We observed the change of La0.5Sr0.5CoO3 /SiO2/Si films' resistence when the film was immersed in the water and analyzed the possible reason of the change.4. We get the dependence between resistence and temperature and humidity of the La0.5Sr0.5CoO3 target and the La0.5Sr0.5CoO3/SiO2/Si films.5. We find that the La0.5Sr0.5CoO3 films on the gradient LaAlO3 substrates have LITV effective. And we find that the LITV response time is shorter than the LaCaMnO3 film's. In addition, we find the LITV effect on the La1-xSrxCoO3 films(x=0.3, 0.6) which are grown on the gradient LaAlO3 substrates.
Keywords/Search Tags:Pulsed Laser Deposition (PLD), La0.5Sr0.5CoO3, Humidity, R-T, Laser Induced Thermoelectric Voltage
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