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Anodic Dissolution Of White Noise Of The System Model Of Electrochemical Oscillations Induced By The Simulation Study

Posted on:2007-08-13Degree:MasterType:Thesis
Country:ChinaCandidate:F ZhangFull Text:PDF
GTID:2191360185964543Subject:Physical chemistry
Abstract/Summary:PDF Full Text Request
The noise exists everywhere in the world. It's reported that noise took an important role in the evolutive process of nonlinear system. Noise research has been given more and more attention by many workgroups came from different countries and many reports about this new hotspot had been published on the top level journals, such as Science, Nature, JPC, CPL in the recent decade. Mostly, the aim of noise research is to understand and explain the dynamic behavior induced by noise under unbalanced state in the different systems. The aim of this study is to investigate the nonlinear dynamic behavior induced by noise in electrochemical oscillated-system.In the first chapter, the research headway, the basic knowledge of mode solution, several famous modes, in particulate the background and characteristics of electrochemical oscillation, have been introduced in detail. The fact that electrochemical oscillated-system is easy to be given signal, observed and widely exist in bio-system made it more significant to study electrochemical oscillated-mode than normal chemical oscillated-mode.In the second chapter, the basic concepts and knowledge of nonlinear dynamics of chemistry, and research background of nonlinear science as well were described in detail. Application of nonlinear dynamics of chemistry was reviewed, and its research progress and the Dissipative Structure Theory were included. The Dissipative Structure Theory has a big impact on the research of nonlinear dynamics of chemistry. Next, this chapter investigated the effect of noise on the nonlinear dynamics of chemistry, the important phenomenon of stochastic resonance induced by noise in nonlinear system. The S/N ratio of a two state model was established by studying the token method at length.Explicit internal signal stochastic resonance is investigated when white noise is added to the region of periodic-2 oscillatory state in a electrochemical model for anode dissolve oscillations .The signal-to-noise ratio (SNR) of internal signal has a maximum value induced by white noise. It is found that the SNR of strong signal is increasing faster than the weak signal whit the same noise intensity . In contrast, the frequencies of both signals keep constant whit the increment of noise intensity. The simulations showed that the intrinsic signals were selectivity induced by noise and the system can sustain intrinsic period oscillatory states to...
Keywords/Search Tags:explicit internal signal stochastic resonance, white noise, electrochemical oscillations, coupled, anode dissolve
PDF Full Text Request
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