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Nanoparticles, And Mixtures Thereof Fluidization In The Fluidized Bed Of Magnetic Field

Posted on:2008-07-20Degree:MasterType:Thesis
Country:ChinaCandidate:P CengFull Text:PDF
GTID:2191360215985757Subject:Chemical Engineering
Abstract/Summary:PDF Full Text Request
The fluidization behavior of SiO2, ZnO, TiO2 and Al2O3nanoparticles in glass pip with diameter of 4 mm is investigated. Thereexisted fixed bed, plug formation, and channeling at the low superficialgas velocity. There exist two areas even at high gas velocities for SiO2,TiO2 and Al2O3 nanoparticles in traditional fluidized bed, smallagglomerate bubbling fluidized (ABF) area at the upper and bigagglomerate de-fluidized area at the bottom. By adding cast iron particleswith the average size of 2mm into the fluidized bed as magnets, bigagglomerates and channeling formed by SiO2 nanoparticles at lowsuperficial gas velocity were broken up then, the bubbling and elutriationwere also restrained because cast iron particles vibrated violently abovethe distributor under oscillating magnetic filed engendered by a magneticstator and AC current.The agglomerate particle fluidized (APF) of SiO2 nanoparticlesshowed liquid-like properties and the agglomerates circulated in thefluidized bed just like fluid. When the fluidization ability of ZnO, TiO2and Al2O3 nanoparticles was poor in a traditional fluidized bed or even inthe magnetic fluidized bed with adding coarse magnets, the fluidizedSiO2 nanoparticles were used as the fluidized medium in order to improvetheir fluidization ability. It was found that homogeneous mixtures formedwhen ZnO nano-particles were added in the fluidized bed of SiO2nanoparticles, and the maximum mass fraction of nano-ZnO that canform homogenous mixtures is more than 90%. The stable operation areaof the APF was determined by the mass fraction of additivenano-particles and magnetic field intensity, and the stable operation areadecreased with increasing the mass fraction of additive nano-particles.Finally, the Matsuda's model and the Richardson-Zaki equation wereused to check the relation between the agglomerate size and the minimumfluidization superficial gas velocity of SiO2 nanoparticles and theexpansion degree of nanoparticle mixtures, respectively. Model forestimating the terminal velocity of the mixture formed by APF and ABFnano-particles is proposed for further research in mixed nano-particles and its application in the future.
Keywords/Search Tags:Nano-particles, fluidization, magnetic fluidized bed, coarse magnets, mixture
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