Synthesis Of β-Diketiminato Complexes Based On Phenylethylamine

Since 1989, a kind of new late-transition metal compounds catalysts for polymerization have been developed quickly. Compared with the metallocene catalyst, it has a better advantage. Based on our group's research work, my research focused on the field ofβ-diketiminato organometallic chemistry.On the basis of experimental subjects, (S)-a-phenylethylamine was used to synthesizedβ-diimine and its metal organic compounds. The main research work consists of these parts:(1) study and synthesis ofβ-diketiminato ligand and its metal compounds; (2) study and synthesis of azaallyl ligands and metal compounds; (3) attempts for synthesis of silyl-bridged compounds.Chapter 1. The fist chapter describes the history and background of this thesis:(1) the introduction of the imine and its metal complexes; (2) synthetic method, coordination mode and progress ofβ-diketiminato metal complexes; (3) synthesis and characteristic of azaallyl metal complexes.Chapter 2. Synthesis of P-diketiminato alkali ligands and its metal compounds from a-phenylethylamine.Chapter 3.Synthesis of azaallyl ligands and its metal complexes.Chapter 4.Attempts to synthesize silyl-bridged compounds from a-phenylethylamin...