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Synthesis Of β-Diketiminato Complexes Based On Phenylethylamine

Posted on:2012-01-03Degree:MasterType:Thesis
Country:ChinaCandidate:L ShangFull Text:PDF
GTID:2211330368489608Subject:Applied Chemistry
Abstract/Summary:PDF Full Text Request
Since 1989, a kind of new late-transition metal compounds catalysts for polymerization have been developed quickly. Compared with the metallocene catalyst, it has a better advantage. Based on our group's research work, my research focused on the field ofβ-diketiminato organometallic chemistry.On the basis of experimental subjects, (S)-a-phenylethylamine was used to synthesizedβ-diimine and its metal organic compounds. The main research work consists of these parts:(1) study and synthesis ofβ-diketiminato ligand and its metal compounds; (2) study and synthesis of azaallyl ligands and metal compounds; (3) attempts for synthesis of silyl-bridged compounds.Chapter 1. The fist chapter describes the history and background of this thesis:(1) the introduction of the imine and its metal complexes; (2) synthetic method, coordination mode and progress ofβ-diketiminato metal complexes; (3) synthesis and characteristic of azaallyl metal complexes.Chapter 2. Synthesis of P-diketiminato alkali ligands and its metal compounds from a-phenylethylamine.Chapter 3.Synthesis of azaallyl ligands and its metal complexes.Chapter 4.Attempts to synthesize silyl-bridged compounds from a-phenylethylamin...
Keywords/Search Tags:β-Diketiminato, Synthesis, Azaallyl
PDF Full Text Request
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