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Theoretical Research On The Ion Of Se31+(1s2np-1s2n’d) Transition Behavior With The Full Core Plus Correlation Method

Posted on:2014-11-20Degree:MasterType:Thesis
Country:ChinaCandidate:Q LiuFull Text:PDF
GTID:2250330425969125Subject:Atomic and molecular physics
Abstract/Summary:PDF Full Text Request
At the first of this paper,provides an overview to the scope of atomic and molecularphysics.Then this article introduce the multi-electron atom structure,however,the highlycharged ions have been an important reach area to be illustrated.The FCPC method isextended to be calculated the energy structure of1s2nl (l=p,d;n≤9) states of Se31+ion.Thestates include ionization energy;excitation energy and transition energy.After these,the articlealso details the principle and the achievement of Full-core plus correlation with brief words,Inorder to obtain the high-precision theoretical results.At the same time,the contributions fromhigher angular momentum partial wave and the core-correction are also involved.In thecalculation of the fine structure splitting for these states,spin-orbit,spin-other-orbitinteractions,QED contribution and high-order relativistic contribution.The results of this workgenerally agree with some literatures.In addition,this paper calculate the dipole osscillator strengths of1s2np-1s2n′d(2≤n≤9,3≤n′≤9)with the Se31+ion in FCPC wave functions,Finally,according to the theory ofQDT,calculated Se31+ion1s2np-1s2n′d(2≤n≤9,3≤n′≤9) with the quantum defect theory to theion energy and oscillator strength of the theroy predicted accuratelly extrapolated to includethe entire cotinuum state to the domain.
Keywords/Search Tags:Se31+ion, Ionization potential, Quantum defect, Oscillator strength
PDF Full Text Request
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