Font Size: a A A

Study On Preparation And Arc Erosion Resistance Of Dispersion Strengthened Copper Matrix Composites

Posted on:2014-12-26Degree:MasterType:Thesis
Country:ChinaCandidate:S L LiFull Text:PDF
GTID:2251330422456524Subject:Materials Processing Engineering
Abstract/Summary:PDF Full Text Request
The main feature of dispersion strengthened copper matrix composites is thatceramic phase particles with great physical and chemical stability, such as Al2O3, CrO2,TiB2, SiC, etc., are dispersed in the copper matrix uniformly and finely. Theconductivity and strength of dispersion strengthened copper matrix composites are notonly good at room temperature, but also at a high temperature. Dispersionstrengthened copper matrix composites have potential applications in electrical contactareas, such as high-speed railway catenary systems, high pressure switch contact,microelectronics and electrical control. Fabrication methods, content or size of thedispersion particle are key factors affecting the performance and arc erosion resistanceof dispersion strengthened copper matrix composites.Al2O3/Cu composites were respectively fabricated by internal oxidation, coldsintering and SPS in this paper. The effects of different fabricated methods onproperties of Al2O3/Cu composites, such as density, hardness and electricalconductivity, were studied. With TiB2/Cu composites as studying objects, the effects ofTiB2content on arc erosion resistance of TiB2/Cu composites were studied. WithAl2O3/Cu composites as studying objects, the effects of Al2O3size on arc erosionresistance of Al2O3/Cu composites were studied.The results showed that:1. The Al2O3particles in the Al2O3/Cu composites fabricated by internaloxidation were uniformly dispersed in the coppor matrix in fine grain. Thecomprehensive properties of the Al2O3/Cu composites fabricated by internal oxidationwere better than. cold sintering and SPS. Agglomeration of Al2O3nanoparticlesemerged in the Al2O3/Cu composites fabricated by cold sintering as well as SPSmethod, which affected the comprehensive properties of the Al2O3/Cu composites. Thedensity and electrical conductivity of the Al2O3/Cu composites fabricated by coldsintering were lower than internal oxidation and SPS. The density and electrical conductivity of the Al2O3/Cu composites fabricated by SPS were higher than internaloxidation and cold sintering, which reached99.18%and96%IACS respectively. Butdue to the lack of subsequent processing, the hardness was relatively lower. TheAl2O3/Cu composites fabricated by cold sintering were relatively denser with smallergrains.2. In the experimental range, the density and conductivity of the TiB2/Cucomposites were gradually reduced with the TiB2content increasing, and the hardnesswas increased at first and then decreased subsequently, which due to agglomeration ofTiB2nanoparticles in TiB2/Cu composites with TiB2content increasing. The hardnessand electrical conductivity respectively reached75.9HBS and86.3%IACS when theTiB2content of the TiB2/Cu composites reached3.0vol.%. Arc energy of the TiB2/Cucomposites was increased with the TiB2content increasing. The microstructureobservation showed that the arc erosion melting degree on composites surface wasreduced and the overall erosion area was decreased with the TiB2content increasing.And arc erosion resistance of the TiB2/Cu composites was enhanced with TiB2contentincreasing.3. Arc erosion resistance of Al2O3/Cu composites did not show a certain trendwith Al2O3particles size increasing. The surface of Al2O3/Cu composites with Al2O3particle size of100nm was relatively flat, which showed good arc erosion resistanceand had the lowest arc energy.
Keywords/Search Tags:Nanoparticles, dispersion strengthening, copper matrix composites, spark plasma sintering, arc erosion resistance
PDF Full Text Request
Related items