Study On The Selective Reaction Of Arylhydrazine And Arylamine Catalyzed By CoPc

Biphenyl and N-arylamine derivatives are important products and intermediatesin current organic synthesis. They have been widely applied in medicines, dyes,pesticides and materials syntheses. Synthetic radical methodology is a useful tool inmodern chemistry, herein we report the synthesis of biphenyl and N-arylaminederivatives catalyzed by CoPc, to our best knowledge, this is the first example.This thesis is composed of two parts: The first part developed the CoPc-catalyzed reaction of arylhydrazine and arylamine to afford2-aminobiphenylderivatives; The second part studied the synthesis of N-arylamine derivativescatalyzed by CoPc/Cu(OAc)2.