Studies On Dehydration Kinetics Of Talc With Different Iron Content

Subduction zone is a distinct activity structure of hypocenter distribution of earthquakes.Hydrous minerals are involved in the chemical and physical activities in subduction zones.As a widely distributed hydrous mineral in shallow depths,talc has potential significance in various fault activities,and its dehydration reaction may be an important cause of the earthquake..Iron is a main element of the earth's crust,and the iron contents of hydrous minerals have a large impact on melting point,the rheological strength physical and chemical properties of the rocks.As a common hydrous mineral,the iron content of talc is not uniform;therefore,it is very important to study the dehydration kinetics of talc with different iron content.In this study,the dehydration reaction of three different iron content talcs was studied by means of synchronous thermal analysis,high temperature and high pressure differential thermal experiment and in-situ synchrotron X-ray diffraction experiment.Data of synchronous thermal analysis was calculated by Flynn-Wall-Ozawa(FWO).The activation energies of different iron content talc were calculated as E1 =359.8kJ/mol(FeO:0.4wt%)?n1 = 1.6,E3 =368.2.0kJ/mol(FeO:2.0wt%),n3 = 1.8,belonging to the second-order reaction.Data of in-situ synchrotron X-ray diffraction experiment was fitted by Avrami equation,E=350kJ/mol(FeO:2.0wt%),n=1.67.The dehydration of talc followed random nucleation and growth mechanism.High content of iron obviously resulted in lower dehydration temperature.The results show that the dehydration of talc is divided into two stages:the first stage is the migration of hydroxyl groups and the process of partial proton migration,it is not affected by the diffusion;the second stage is the integrated process of the hydroxyl dehydration,proton migration,it is affected by the diffusion control.An increase in the iron content leads to a decrease in the temperature of the first dehydration stage of the talc and an increase in the temperature of the second dehydration stage.The release rate of talc dehydration fluid was 2.3E-05m3fluidm-3rocks-1 to 6.1E-06m3fluidm-3rocks-1 obtained by in-situ synchrotron X-ray diffraction experiment,it can lead to local overpressure induced rock brittle fracture.The supercritical fluid produced by the dehydration of talc in the subduction zone further attenuates the rock,resulting in local overpressure,which eventually leads to rock failure.The results suggested that the dehydration of different iron contents of talc may occur at the different depth around hundreds of kilometers,so the study was significant to our understanding of the genetic mechanism of earthquakes in the subduction zone.