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SnS2-based Composite Material Can Be Controlled And Its Performance Of Photocatalytic Reduction Of Cr???

Posted on:2021-05-16Degree:MasterType:Thesis
Country:ChinaCandidate:X C XingFull Text:PDF
GTID:2381330614453923Subject:Chemical Engineering and Technology
Abstract/Summary:PDF Full Text Request
in the list of priority pollutants.The visible light-driven semiconductor photocatalytic reduction of hexavalent chromium aqueous solution has simple and convenient operation,environmental protection,low cost,high efficiency,reusable,and can be used directly unlimited,Clean,safe natural solar energy and other obvious advantages,therefore,the semiconductor photocatalytic reduction method is an effective method to deal with Cr???aqueous solution.The semiconductor metal sulfide SnS2 has strong visible light response,but due to photocorrosion,SnS2 is unstable as a photocatalyst,and the photogenerated electrons and holes of SnS2 are easily recombined with each other,resulting in poor photocatalytic performance and limiting its practical application.The research content of this paper is as follows:hydrothermal method,and based on SnS2,composite Ni Al-LDH/SnS2 with different amounts of Ni Al-LDH added was prepared by hydrothermal method.The effects of the amount of Ni Al-LDH added on the photocatalytic performance of the composite Ni Al-LDH/SnS2 were investigated through characterization.At pH=3,the reduction of hexavalent chromium to trivalent chromium was used as a probe reaction to investigate the photocatalytic performance and stability of the composite Ni Al-LDH/SnS2.According to the experimental results,when the addition amount of Ni Al-LDH is 0.02 g,Ni Al-LDH/SnS2?0.02? has the best photocatalytic performance and better stability.Using SnS2 as the substrate,composite Ni Fe-LDH/SnS2 with different amounts of Ni Fe-LDH was successfully prepared in the reactor using hydrothermal method.Through experimental characterization,the effect of the amount of Ni Fe-LDH added on the photocatalytic performance of the composite Ni Fe-LDH/SnS2was investigated.At p H=3,the reduction of hexavalent chromium to trivalent chromium was used as the probe reaction,and the photocatalytic performance and stability of the composite Ni Fe-LDH/SnS2 were investigated.According to the experimental results,when the amount of Ni Fe-LDH added is 0.02 g,the photocatalytic efficiency of Ni Fe-LDH/SnS2?0.02? is as high as 99.72%,and it has good stability.Using SnS2 as the base,composite g-C3N4/SnS2with different amounts of g-C3N4was successfully prepared in the reactor by hydrothermal method.Through experimental characterization,the effect of the amount of g-C3N4added on the photocatalytic performance of the composite g-C3N4/SnS2 was investigated.At p H=3,the reduction of hexavalent chromium to trivalent chromium was used as a probe reaction to investigate the photocatalytic performance and stability of the composite g-C3N4/SnS2.According to the experimental results,when the amount of g-C3N4 added is 0.07 g,the photocatalytic efficiency of g-C3N4/SnS2?0.07?is as high as 100%,and it has good stability.
Keywords/Search Tags:SnS2, hydrotalcite, photocatalysis, Cr(?)
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