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Development of a basic numerical model of an isooctane catalytic autothermal reformer for an automobile

Posted on:2005-10-07Degree:M.Sc.(EngType:Thesis
University:Queen's University at Kingston (Canada)Candidate:Li, Vincent Cheuk LamFull Text:PDF
GTID:2451390008481609Subject:Engineering
Abstract/Summary:
A reformer is a device that converts hydrocarbon fuel to a hydrogen-enriched stream for fuel cell operation. A numerical modeling study of the performance of an isooctane catalytic autothermal reformer for a fuel cell automobile has been undertaken.; The flow within the reformer was assumed to be steady. The different chemical reactions, along with the reaction rate constants, that take place over the autothermal reforming catalyst (a ceria-based platinum catalyst), were obtained through the analysis and regression of the experimental results in a previous study.; By neglecting the radial gradients in the concentrations and the velocities of the various species in the flow and in the temperature of the reformer, a one-dimensional numerical model, based on the molar flow rate differential equations and energy equation, was developed to simulate the composition and temperature profiles along the length of the catalyst bed.; In order to investigate the effectiveness of heat transfer between the tubes of the prototype reformer, the heat transfer across the tubular wall was simulated in the one-dimensional numerical model.; In addition to the previously discussed numerical model, a preliminary two-dimensional finite-volume computational fluid dynamics (CFD) model was constructed to investigate the flow field within the prototype reformer. (Abstract shortened by UMI.)...
Keywords/Search Tags:Reformer, Model, Autothermal, Flow
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