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Synthesis and characterization of vegetable oil-based polyurethane dispersions

Posted on:2014-09-15Degree:Ph.DType:Thesis
University:Iowa State UniversityCandidate:Garrison, Thomas FFull Text:PDF
GTID:2451390008954481Subject:Chemistry
Abstract/Summary:
This dissertation discusses the synthesis and characterization of environmentally-friendly waterborne vegetable oil-based polyurethane dispersions and their resulting films. The thermal and mechanical properties of the polyurethane films have been studied using tensile testing, differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. The cationic polyurethane dispersions have potential applications as coatings for food packaging materials due to their antimicrobial activity. Grafted hybrid latexes have been prepared by grafting vinyl monomers onto the polyurethane dispersions via seeded emulsion.
Keywords/Search Tags:Polyurethane dispersions, Synthesis and characterization
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