Transport and lipid solubility of hydrophobic organic compounds using semipermeable membranes: Influence of dissolved organic matter and solution chemistry | Posted on:2003-07-20 | Degree:M.S | Type:Thesis | University:Rice University | Candidate:Dalton, Sarah Kathryn | Full Text:PDF | GTID:2461390011488616 | Subject:Engineering | Abstract/Summary: | | Association of hydrophobic organic compounds with dissolved organic matter in natural water systems may impact a contaminant's ability to transport across synthetic membranes. Importantly, these interactions can create interferences when monitoring ambient levels of contaminants with a potential for biouptake. The influence of water-quality matrix conditions on the transport and lipid uptake of five hydrophobic organic compounds of environmental concern was investigated by partnering semipermeable membranes with a model lipid phase in a batch dialysis system. Contaminants fell into two characteristic groups based on the response of transport and lipid uptake to exposure conditions: one for which behavior was largely independent of water-quality matrix conditions and one for which alterations to the bulk aqueous phase were impactful. For short exposure periods, the abiotic technique demonstrated the potential to qualitatively replicate the root-to-shoot translocation behavior of non-ionized hydrophobic organic compounds in plant systems. | Keywords/Search Tags: | Hydrophobic organic compounds, Transport and lipid, Semipermeable membranes, Water-quality matrix conditions | | Related items |
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