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Reactivity and intramolecular migration chemistry of transition-metal silylene complexes

Posted on:1999-07-21Degree:Ph.DType:Thesis
University:University of California, BerkeleyCandidate:Mitchell, Gregory PaulFull Text:PDF
GTID:2461390014471229Subject:Inorganic Chemistry
Abstract/Summary:
This thesis describes the first reactivity studies of ruthenium silylene complexes and the intramolecular migration chemistry of rhodium, iridium, and platinum silylene complexes.;Reactions of ruthenium silylene complexes of the type (Cp*(PMe;The intramolecular rearrangements of Rh(I) and Ir(I) silyl complexes were studied. Reaction of ;Intramolecular 1,2-hydride migrations involving platinum silylene ligands were investigated. Reaction of the platinum silyl cis-...
Keywords/Search Tags:Silylene, Intramolecular, Complexes
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