This thesis describes the first reactivity studies of ruthenium silylene complexes and the intramolecular migration chemistry of rhodium, iridium, and platinum silylene complexes.;Reactions of ruthenium silylene complexes of the type (Cp*(PMe;The intramolecular rearrangements of Rh(I) and Ir(I) silyl complexes were studied. Reaction of ;Intramolecular 1,2-hydride migrations involving platinum silylene ligands were investigated. Reaction of the platinum silyl cis-... |