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Adsorption of N-hexane, methanol and water vapor and binary mixtures of N-hexane/water vapor on super activated carbon nanoparticles

Posted on:2016-08-18Degree:M.SType:Thesis
University:Texas A&M University - KingsvilleCandidate:Prado, Jesus AntonioFull Text:PDF
GTID:2470390017978997Subject:Environmental Engineering
Abstract/Summary:
Recent times have seen a large rise in the utilization of engineered nanomaterials (ENMs) within a wide variety of industries due to their unique properties. Consequently, the fabrication, application and disposal of ENMs will inevitably lead to their release to the environment. Once ENMs are in the environment, they may undergo atmospheric transformations, such the sorption of hazardous air pollutants (HAPs) or water vapor. These transformed ENMs may then affect the general public through inhalation -- or other pathways of exposure -- and those employed by the ever-growing nanotechnology sector are of particular vulnerability. As a result, it is important to evaluate the adsorption characteristics of a common carbon-based ENM under the presence of HAPs or water vapor which may adsorb onto them. This study investigated the unary and binary gas-phase adsorption of n-hexane, methanol and water vapor on super activated carbon nanoparticles (SACNPs) with a bench-scale adsorption system. Removal efficiencies, breakthrough tests, throughput ratios, adsorption capacities and kinetics modeling were completed to assess the adsorption behavior of the SACNPs.
Keywords/Search Tags:Adsorption, Water vapor, Enms
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