Novel early-transition-metal phosphido species have been prepared and used as "metalloligands" in the synthesis of heterobimetallic complexes.;Reaction of TiCl;Heterobimetallics demonstrating activation of a CO ligand have been prepared via redox reactions of (CpMo(CO);In the course of preparing bimetallics from Ti(III) phosphides, the physical and structural properties of these starting materials were examined. (Abstract shortened by UMI.). |