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Early-transition-metal phosphides and their application towards the synthesis of heterobimetallic complexes

Posted on:1992-12-07Degree:Ph.DType:Thesis
University:University of Windsor (Canada)Candidate:Dick, David GeorgeFull Text:PDF
GTID:2471390014498612Subject:Chemistry
Abstract/Summary:
Novel early-transition-metal phosphido species have been prepared and used as "metalloligands" in the synthesis of heterobimetallic complexes.;Reaction of TiCl;Heterobimetallics demonstrating activation of a CO ligand have been prepared via redox reactions of (CpMo(CO);In the course of preparing bimetallics from Ti(III) phosphides, the physical and structural properties of these starting materials were examined. (Abstract shortened by UMI.).
Keywords/Search Tags:Early-transition-metal, Phosphides, Synthesis, Heterobimetallic
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