Study On The Auto-oxidation Promoted Sp~3C-H Arylation Of Glycine Derivatives | Posted on:2020-09-14 | Degree:Master | Type:Thesis | Country:China | Candidate:Y Y Wei | Full Text:PDF | GTID:2481305741462114 | Subject:Organic Chemistry | Abstract/Summary: | PDF Full Text Request | This thesis is divided into two parts.The first part briefly reviews the research progress of cross-dehydrogenation coupling reaction of glycine derivatives,including the following two aspects:(1)C-C bond coupling reaction;(2)C-heteroatom bond couplingling reaction.The second part mainly introduces my research results during my master's degree.Sp~3C-H arylation of N-arylglycine derivatives with electron-rich arenes cross-dehydrogenative under auto-oxidation is described in this paper.This atom-economical and environmentally benign reaction proceeds smoothly under mild reaction conditions,and the possible radical involved mechanism is proposed. | Keywords/Search Tags: | auto-oxidation, Glycine derivatives, N,N-Dimethylaniline, arylation | PDF Full Text Request | Related items |
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