Nuclear magnetic resonance of laser-polarized noble gases in molecules, materials, and organisms | Posted on:2000-08-15 | Degree:Ph.D | Type:Dissertation | University:University of California, Berkeley | Candidate:Goodson, Boyd McLean | Full Text:PDF | GTID:1460390014462332 | Subject:Chemistry | Abstract/Summary: | | Conventional nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) are fundamentally challenged by the insensitivity that stems from the ordinarily low spin polarization achievable in even the strongest NMR magnets. However, by transferring angular momentum from laser light to electronic and nuclear spins, optical pumping methods can increase the nuclear spin polarization of noble gases by several orders of magnitude, thereby greatly enhancing their NMR sensitivity.;This dissertation is primarily concerned with the principles and practice of optically pumped nuclear magnetic resonance (OPNMR). The enormous sensitivity enhancement afforded by optical pumping noble gases can be exploited to permit a variety of novel NMR experiments across many disciplines. Many such experiments are reviewed, including the void-space imaging of organisms and materials, NMR and MRI of living tissues, probing structure and dynamics of molecules in solution and on surfaces, and zero-field NMR and MRI. | Keywords/Search Tags: | Nuclear magnetic resonance, NMR, MRI, Noble gases | | Related items |
| |
|