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Activities Of Improve-Loaded TiO2 Photocatalyst Application In Treatment H2S Odor

Posted on:2009-09-25Degree:MasterType:Thesis
Country:ChinaCandidate:S X LiFull Text:PDF
GTID:2121360245952084Subject:Environmental Engineering
Abstract/Summary:PDF Full Text Request
Activities of TiO2-photocatalyst which fixed on the glass fiber by means of the sol - Gel method of titanium Sol and impregnated - pulling method in degradation H2S odor has been investigated on the self-made gas - solid reaction. The oxygen content, relative humidity and gas concentration have been taken into account to study the activities of improve-loaded TiO2 photocatalyst application in treatment H2S odor. In addition, photocatalytic principle has been used to explain the problems in the study, explored the way to improve catalyst active by modified- TiO2. This research gives basic data and the theoretic support in order to Industrial application with TiO2- photocatalyst in degradation H2S odor.Glass fiber cloth as the carrier, TiO2 photocatalyst is more active in degradation H2S odor which decreases particle size after Ag doping and strong acid surface treatment by XRD technology. This is became the initial reaction of the optical principles and TiO2 modified principle.Object to the degradation H2S, oxygen content, relative humidity and H2S initial concentration factors on the impact of TiO2- photocatalyst Activities have been controlled. Statistical analysis of experimental data obtained that when the oxygen content of 25%, relative humidity of 20%, TiO2 degradation H2S effect is the best. Time will control degradation effect, this experiment intake of 100 mg/m3, the system dealing with H2S efficiency is more than 80 %, with the increasing concentration of intake, efficiency dropped drastically.In addition, the impact of the relative humidity was discussed. H2O molecule plays a dual role, on the one hand, higher relative humidity conditions will promote the H2O molecule H2S initial stage of purification rate; On the other hand, In smaller relative humidity conditions of competition H2O absorption of the weakening of TiO2 on H2S more thorough cleaning TiO2. In different relative humidity conditions modified-TiO2 are relatively stable performance from the excellent catalytic performance.
Keywords/Search Tags:H2S, Ag/TiO2, SO42-/TiO2
PDF Full Text Request
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