Groundwater flow dynamics and contaminant transport to coastal waters under low recharge conditions: Regional-scale study of the aquifer system underlying southern Baldwin County, Alabama

This study examined the influence of drought conditions and increased hydrological stresses on the groundwater system flow dynamics, submarine groundwater discharge, and nitrate transport and discharge to the Gulf of Mexico. The results of these studies demonstrate that current stresses on the aquifer have led to significant saltwater intrusion and or direct infiltration into fresh groundwater, especially within the upper aquifers of the region. The nitrate and chloride data analyses reveal the persistent presence of multiple nitrate impacted zones within the study area. Stable isotope data support the hypothesis that nitrate in the investigated aquifers originates from the nitrification of ammonium in soils from a mixture of sources ranging from fertilizer to sewer and/or manure and that denitrification, the breakdown of nitrates to nitrogen gas, is not significant in the investigated aquifer system. Furthermore, groundwater isotope data indicates that water in the aquifer system of the study area is most likely to have originated from precipitation and soil infiltration through relatively localized recharge and that the aquifer system in the study area is highly dynamic, experiencing mixing of recent recharged waters with older, ambient groundwaters. The presence of low residence times and the absence of denitrification reveal the oxic character of this system. As a proxy for a number of contaminant types, the groundwater flow and transport model was used to simulate nitrate transport in response to variable-density groundwater flow. The simulation results indicate that in the investigated aquifer system complexities arise because groundwater flow dynamics and contaminant transport are additionally influenced by density variations that can occur from the incursion of saltwater.;The model predicts that the Beach Sand and Gulf Shores Aquifers will be impacted by severe saltwater intrusion whereas the deeper 350 and 500-Foot Aquifers will experience no saltwater intrusion for the entire simulation period. Consequently, nitrate discharge to the Gulf of Mexico originates from the lower part of the aquifer system through submarine groundwater discharge. This research will serve as a tool which may be applied to other similar coastal systems for more effective management strategies.