| ANSmCTIn thes thesis, two kinds including fifteen novel POlydentae pendan-armedcalix[4]aren derivatives were synthesind. Among the derivatives synthsind fivesingle crystals were obtalned. Their StrUCtUres and confOrmations wercMtw. Their properties and aPPlications in solven extraction. liquldmembran haPOrt, PVC membran ionselective electrode and sensitiringlurninescence of lanthhode comPlexes were StUdied. The main resultS obtuined areas follows.l. The fOllowing l2 killds of new polydentate pendan-anned calis[4]arenederivatives were designed and synthwt. All of the compounds wercharaterital by elemental analysis, IR and NMR. They are in cone orl .3-altCot COnfOrmations.ha wrgOR' OR" 4.6 m-, tuu, KXH3 6Me7 m=3, Rndu, ReqH3, R'=H8 m=2, Rwhu, R'edH3, RWeH (lJdiStaI) l3 R~Bu9 m-, R=H, ReqH3 l4 R=HI0 m=2, Rm, eq, R-H (l,3distaI)l l ed, Rwh' mp3l2 m=3, Rwh' ro3, mpEtl5 m=4, ny ffeHl6 m=3, R=tBu. R-H. R~Hl7 m=2, RopBu, R-H, RWeH (l,3diml)The recoghtion of alkali metal cations by comPOunds 6-14 was studiedusing solvefit exthetion, liquid membrane twPOrt, PVC membran ion-selectiveelectrode. ComPOunds 6, 9 and ll exhibit high selective extractibility for K+, theorder of the selectivity is K+>Na+>Cs+>Li+. ComPOUnds 6 and 1l give the highestextractibility for K+, the percentages of etation are 80.9% and 69.8% in theCendn condition, respectively. The IH Nam SpeCtra indicated that the phenoloxygen atoms and carbonyl oxygen atoms paticiPae in the coordination for K+ incompound 6 and l1. PVC membrane iOnselective electrod PrePared by usingcompound 6 or 1l as the cAner, dioctyl sebacate as the plasticizer and KTPClPBas the ionic site, ndbit high Nerstian reSPOnse charaCtbocs for K+. The linearpe ranec Of cowds 6 anu 11 ror c are 10xl0l an0 l0xl0'mat;the corresponding sloPes are 54.8 and 56.0mVldecad, reSpectively PotenometricseleCtivity coefficients for K+ and Na+ (logKry+.N.) of COmPOUns 6 and l1 are-l. l4 and -l .69, resPectivelyThe PrOPethes of compounds ca and 12-17 fOr senShan lumineSCenCe ofrare earth cations were studied. The resuItS indicated tha the comPOunds lSl7tw ammatic tw grOuP have the most remahale effec on the sensihZingluminscence of Tb,+ and Eus+ (exCePt compound l7 for Eu3b aInon the tencoHunds. Compounds 7 and 8 with hydrDxyI gIDuP hav lesser effeCt on thesensitizin luminscence of Tb3+. The tetrasubnituted compoUnds 6, 9 and 12-14W no eviden effeCt on the sensitizin ltnnineSCene of Th3+. The tenzen ringSin bons and PeN anns can N the M of ultraviolet and effeCtivelywt it to rare eed catons. The efficiency of sensittalng luInineScence isrelated to the steric hintwe of the ligands and the stability of the comPlexes. TheM[4]m derivedwe forg areInatic Ai M can effedvely edzethe luminerence of Th,+ and Eu+. They are a good kind of lumtheSCenior withMnna effeCt.2. The crystal wtwts of compounds 6, 8, 9, l6 and l7 wer ddsnnined.There ekiSt intramlecular hydrogen bond in the molecules of coInpounds 8, 16and l7, intermolecular hydrOgen bond in coIUPOW l6 and l7 and italecular7t-n interachon in compounds 8, 9, 16 and l7. The suPramlecules were formed bythese intwlecular iNaction thrOugh molecular selfassemly in COInPOUn 8,9, 16 and l7. The resultS demonStrated tha the ~ factrs detetrining thePacking pattem of the molecules are the natUre and nUInber of the Pendan armgrouPs and the confOnnaion of calixl4]arene derivatives.a. The following three calix[41arene derivatives bearing nexiblecoordinaing ann grOuPs were designed and synthesized. All of the comPOundswere chaW by elemental analysis and NMR. They are in cone orI,3-altema COnfonnationS.Ai +ty ry; (i"vi ct",zs23 n=lM nnThe recogultion of alkali metal cations by compounds 23-25 was studiedusing solven extwon, liquld memtw ~rt, PVC memfor ion-seleCiveclCCtrod. All of the bo compounds hav higher seleChe exwtility fOr Cs+,the onier of the seleCtivity is...
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