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Biomineralization and biosorption involving bacteria: Metal phosphate precipitation and mercury adsorption experiments

Posted on:2014-09-18Degree:Ph.DType:Dissertation
University:University of Notre DameCandidate:Dunham-Cheatham, Sarrah MFull Text:PDF
GTID:1451390005989527Subject:Biogeochemistry
Abstract/Summary:
The research conducted in these chapters focused on the transport and fate of a range of metals in the presence of bacteria. In Chapter 2, I investigated the effects of bacteria on the precipitation of metal phosphates and discovered 2 phenomena, passive cell wall mineralization and the decreased size of precipitated minerals due to the presence of bacteria. In Chapters 3 and 4, I investigated the effects of 2 ligands (chloride in Chapter 3, fulvic acid in Chapter 4) on the adsorption behavior on mercury to bacterial cells. I learned from these studies that the presence of ligands can have a range of effects on the adsorption behavior of mercury to bacterial cells.;In all of my investigations, I used thermodynamic models to calculate stability constants for several metal-bacteria complexes formed in my experiments. These stability constants can be used to better predict the behavior of metals in metal-bacteria-ligand systems, which is potentially beneficial to several applications (e.g. developing effective remediation strategies).
Keywords/Search Tags:Bacteria, Mercury, Adsorption
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