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Studies of spin-exchange optical pumping

Posted on:2004-05-14Degree:Ph.DType:Dissertation
University:The University of Wisconsin - MadisonCandidate:Chann, BienFull Text:PDF
GTID:1460390011966656Subject:Physics
Abstract/Summary:
Although we still do not understand fully the alkali-alkali relaxation at pressures of an atmosphere or more, an important part of the spin-relaxation comes from the classical dipole-dipole anisotropic spin-axis interaction acting in triplet dimer molecules. The key observation is the existence of magnetic resonances in the magnetic decoupling curves which are predicted from the spin-axis interaction.; We identified a new gas-phase, room temperature spin relaxation that is due to the spin-rotation coupling in bound 129Xe-Xe van der Waals molecules. This 129Xe-Xe molecular spin-relaxation is more than an order of magnitude stronger than the well-known 129 Xe-Xe binary spin-relaxation and is the fundamental spin-relaxation process at gas densities below 14 amagat.; With external cavity diode laser array bar, we find, based on tests of several cells, that the power required to reach the same polarization is typically three times lower for the spectrally narrowed laser as compared to the unnarrowed diode array bar. This last result indicates that spectrally narrowed lasers are critical to obtaining the highest noble gas polarizations. Furthermore, we find, circularly polarized light propagating at an angle as small as a few degrees to the external magnetic field does not optically pump the atoms to full transparency and causes excess absorption of the pump beam.; We measured the Rb-3He spin-exchange rate coefficients using three different methods. We obtained 6.73 ± 0.12 × 10 −20 cm3/s for the repolarization method. We deduced the spin-exchange rate coefficient to be 6.61 ± 0.12 × 10 −20 cm3/s for the rate balance method. The third method uses a temperature dependence relaxation of 3He and the deduced value is 8.85 ± 0.32 × 10−20 cm3/s. This is about 30% higher than the other two methods. This implies a temperature-dependence wall-relaxation or a large value of anisotropic spin-exchange rate coefficient for Rb-3He and would explain the shortfall 3He measured polarization.
Keywords/Search Tags:Spin-exchange, Relaxation
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